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(Redirected from Ozone generator)
For other uses, see Ozone (disambiguation).
bluish colored gas
2.144 g·L−1 (0 °C), gas
80.7 K, −192.5 °C
161.3 K, −111.9 °C
0.105 g·100mL−1 (0 °C)
Std enthalpy of
Ozone or trioxygen (O3) is a triatomic molecule, consisting of three oxygen atoms. It is an allotrope of oxygen that is much less stable than the diatomic O2. Ground-level ozone is an air pollutant with harmful effects on the respiratory systems of animals. The ozone layer in the upper atmosphere filters potentially damaging ultraviolet light from reaching the Earth's surface. It is present in low concentrations throughout the Earth's atmosphere. It has many industrial and consumer applications.
Ozone, the first allotrope of a chemical element to be recognized by science, was proposed as a distinct chemical compound by Christian Friedrich Schönbein in 1840, who named it after the Greek verb ozein (ὄζειν, "to smell"), from the peculiar odor in lightning storms. The formula for ozone, O3, was not determined until 1865 by Jacques-Louis Soret and confirmed by Schönbein in 1867.
The structure of ozone, according to experimental evidence from microwave spectroscopy, is bent, with C2v symmetry (similar to the water molecule), O – O distance of 127.2 pm and O – O – O angle of 116.78°. The central atom forms an sp² hybridization with one lone pair. Ozone is a polar molecule with a dipole moment of 0.5337 D. The bonding can be expressed as a resonance hybrid with a single bond on one side and double bond on the other producing an overall bond order of 1.5 for each side.
2 O3 → 3 O2
This reaction proceeds more rapidly with increasing temperature and decreasing pressure. Deflagration of ozone can be triggered by a spark, and can occur in ozone concentrations of 10 wt% or higher .
2 Cu+ (aq) + 2 H3O+ (aq) + O3 (g) → 2 Cu2+ (aq) + 3 H2O (l) + O2 (g)
NO + O3 → NO2 + O2
This reaction is accompanied by chemiluminescence. The NO2 can be further oxidized:
NO2 + O3 → NO3 + O2
The NO3 formed can react with NO2 to form N2O5:
NO2 + NO3 → N2O5
C + 2 O3 → CO2 + 2 O2
2 NH3 + 4 O3 → NH4NO3 + 4 O2 + H2O
PbS + 4 O3 → PbSO4 + 4 O2
S + H2O + O3 → H2SO4
3 SO2 + 3 H2O + O3 → 3 H2SO4
3 SnCl2 + 6 HCl + O3 → 3 SnCl4 + 3 H2O
H2S + O3 → SO2 + H2O
H2S + O3 → S + O2 + H2O
3 H2S + 4 O3 → 3 H2SO4
I2 + 6 HClO4 + O3 → 2 I(ClO4)3 + 3 H2O
Solid nitryl perchlorate can be made from NO2, ClO2, and O3 gases:
2 NO2 + 2 ClO2 + 2 O3 → 2 NO2ClO4 + O2
Ozone can be used for combustion reactions and combusting gases; ozone provides higher temperatures than combusting in dioxygen (O2). The following is a reaction for the combustion of carbon subnitride which can also cause lower temperatures:
3 C4N2 + 4 O3 → 12 CO + 3 N2
H + O3 → HO2 + O
2 HO2 → H2O4
Ozonides can be formed, which contain the ozonide anion, O3-. These compounds are explosive and must be stored at cryogenic temperatures. Ozonides for all the alkali metals are known. KO3, RbO3, and CsO3 can be prepared from their respective superoxides:
KO2 + O3 → KO3 + O2
2 KOH + 5 O3 → 2 KO3 + 5 O2 + H2O
CsO3 + Na+ → Cs+ + NaO3
3 Ca + 10 NH3 + 6 O3 → Ca•6NH3 + Ca(OH)2 + Ca(NO3)2 + 2 NH4O3 + 2 O2 + H2
2 Mn2+ + 2 O3 + 4 H2O → 2 MnO(OH)2 (s) + 2 O2 + 4 H+
CN- + O3 → CNO- + O2
(NH2)2CO + O3 → N2 + CO2 + 2 H2O
The distribution of atmospheric ozone in partial pressure as a function of altitude.
Concentration of ozone as measured by the Nimbus-7 satellite.
Total ozone concentration in June 2000 as measured by EP-TOMS satellite instrument.
The standard way to express total ozone levels (the amount of ozone in a vertical column) in the atmosphere is by using Dobson units. Concentrations at a point are measured in parts per billion (ppb) or in μg/m³.
Main article: Ozone layer
The highest levels of ozone in the atmosphere are in the stratosphere, in a region also known as the ozone layer between about 10 km and 50 km above the surface (or between about 6 and 31 miles). Here it filters out photons with shorter wavelengths (less than 320 nm) of ultraviolet light, also called UV rays, (270 to 400 nm) from the Sun that would be harmful to most forms of life in large doses. These same wavelengths are also among those responsible for the production of vitamin D, a vitamin also produced by the human body. Ozone in the stratosphere is mostly produced from ultraviolet rays reacting with oxygen:
O2 + photon(radiation< 240 nm) → 2 O
O + O2 → O3
It is destroyed by the reaction with atomic oxygen:
O3 + O → 2 O2
The latter reaction is catalysed by the presence of certain free radicals, of which the most important are hydroxyl (OH), nitric oxide (NO) and atomic chlorine (Cl) and bromine (Br). In recent decades the amount of ozone in the stratosphere has been declining mostly because of emissions of CFCs and similar chlorinated and brominated organic molecules, which have increased the concentration of ozone-depleting catalysts above the natural background. Ozone only makes up 0.00006% of the atmosphere.
Low level ozone (or tropospheric ozone) is regarded as a pollutant by the World Health Organization and the United States Environmental Protection Agency (EPA). It is not emitted directly by car engines or by industrial operations, but formed by the reaction of sunlight on air containing hydrocarbons and nitrogen oxides that react to form ozone directly at the source of the pollution or many kilometers down wind.
Ozone reacts directly with some hydrocarbons such as aldehydes and thus begins their removal from the air, but the products are themselves key components of smog. Ozone photolysis by UV light leads to production of the hydroxyl radical OH and this plays a part in the removal of hydrocarbons from the air, but is also the first step in the creation of components of smog such as peroxyacyl nitrates which can be powerful eye irritants. The atmospheric lifetime of tropospheric ozone is about 22 days; its main removal mechanisms are being deposited to the ground, the above mentioned reaction giving OH, and by reactions with OH and the peroxy radical HO2· (Stevenson et al., 2006).
There is evidence of significant reduction in agricultural yields because of increased ground-level ozone and pollution which interferes with photosynthesis and stunts overall growth of some plant species.
Certain examples of cities with elevated ozone readings are Houston, Texas, and Mexico City, Mexico. Houston has a reading of around 41 ppb, while Mexico City is far more hazardous, with a reading of about 125 ppb.
Ozone cracking in Natural rubber tubing
Ozone gas attacks any polymer possessing olefinic or double bonds within its chain structure, such materials including natural rubber, nitrile rubber, and Styrene-butadiene rubber. Products made using these polymers are especially susceptible to attack, which causes cracks to grow longer and deeper with time, the rate of crack growth depending on the load carried by the product and the concentration of ozone in the atmosphere. Such materials can be protected by adding antiozonants, such as waxes, which bond to the surface to create a protective film or blend with the material and provide long term protection. Ozone cracking used to be a serious problem in car tires for example, but the problem is now seen only in very old tires. On the other hand, many critical products like gaskets and O-rings may be attacked by ozone produced within compressed air systems. Fuel lines are often made from reinforced rubber tubing and may also be susceptible to attack, especially within engine compartments where low levels of ozone are produced from electrical equipment. Storing rubber products in close proximity to DC electric motors can accelerate the rate at which ozone cracking occurs. The commutator of the motor creates sparks which in turn produce ozone.
Although ozone was present at ground level before the Industrial Revolution, peak concentrations are now far higher than the pre-industrial levels, and even background concentrations well away from sources of pollution are substantially higher. This increase in ozone is of further concern because ozone present in the upper troposphere acts as a greenhouse gas, absorbing some of the infrared energy emitted by the earth. Quantifying the greenhouse gas potency of ozone is difficult because it is not present in uniform concentrations across the globe. However, the scientific review on the climate change (the IPCC Third Assessment Report) suggests that the radiative forcing of tropospheric ozone is about 25% that of carbon dioxide.
There is a great deal of evidence to show that high concentrations of ozone, created by high concentrations of pollution and daylight UV rays at the Earth's surface, can harm lung function and irritate the respiratory system. A connection has also been known to exist between increased ozone caused by thunderstorms and hospital admissions of asthma sufferers. Air quality guidelines such as those from the World Health Organization are based on detailed studies of what levels can cause measurable health effects. Exposure to ozone and the pollutants that produce it has been linked to premature death, asthma, bronchitis, heart attack, and other cardiovascular problems. According to scientists with the United States Environmental Protection Agency (EPA), susceptible people can be adversely effected by ozone levels as low as 40 ppb.
The Clean Air Act directs the EPA to set National Ambient Air Quality Standards for several pollutants, including ground-level ozone, and counties out of compliance with these standard are required to take steps to reduce their levels. In May 2008, the EPA lowered its ozone standard from 80 ppb to 75 ppb. This proved controversial, since the Agency's own scientists and advisory board had recommended lowering the standard to 60 ppb, and the World Health Organization recommends 51 ppb. Many public health and environmental groups also supported the 60 ppb standard. On the other hand, the EPA had already designated over 300 mostly urban counties as out of compliance, and lowering the standard to 75 ppb put hundreds more in non-compliance. Lowering it further to 60 ppb would likely have left most of the US in non-compliance. Manufacturers, employers, and others argued that the cost of compliance with the lower standard would be prohibitive. The EPA has also developed an Air Quality Index to help explain air pollution levels to the general public. Eight-hour average ozone concentrations of 85 to 104 ppb are described as "Unhealthy for Sensitive Groups", 105 ppb to 124 ppb as "unhealthy" and 125 ppb to 404 ppb as "very unhealthy".
Ozone can also be present in indoor air pollution.
A common British folk myth dating back to the Victorian era holds that the smell of the sea is caused by ozone, and that this smell has "bracing" health benefits. Neither of these is true. The characteristic "smell of the sea" is not caused by ozone but by the presence of dimethyl sulfide generated by phytoplankton, and dimethyl sulfide, like ozone, is toxic in high concentrations.
Long-term exposure to ozone has been shown to increase risk of death from respiratory illness. A study of 450,000 people living in United States cities showed a significant correlation between ozone levels and respiratory illness over the 18-year follow-up period. The study revealed that people living in cities with high ozone levels such as Houston or Los Angeles had an over 30% increased risk of dying from lung disease.
See also: trioxidane
Ozone, along with reactive forms of oxygen such as superoxide, singlet oxygen, hydrogen peroxide, and hypochlorite ions, is naturally produced by white blood cells and other biological systems (such as the roots of marigolds) as a means of destroying foreign bodies. Ozone reacts directly with organic double bonds. Also, when ozone breaks down to dioxygen it gives rise to oxygen free radicals, which are highly reactive and capable of damaging many organic molecules. Ozone has been found to convert cholesterol in the blood stream to plaque (which causes hardening and narrowing of arteries). Moreover, it is believed that the powerful oxidizing properties of ozone may be a contributing factor of inflammation. The cause-and-effect relationship of how the ozone is created in the body and what it does is still under consideration and still subject to various interpretations, since other body chemical processes can trigger some of the same reactions. A team headed by Dr. Paul Wentworth Jr. of the Department of Chemistry at the Scripps Research Institute has shown evidence linking the antibody-catalyzed water-oxidation pathway of the human immune response to the production of ozone. In this system, ozone is produced by antibody-catalyzed production of trioxidane from water and neutrophil-produced singlet oxygen.
When inhaled, ozone reacts with compounds lining the lungs to form specific, cholesterol-derived metabolites that are thought to facilitate the build-up and pathogenesis of atherosclerotic plaques (a form of heart disease). These metabolites have been confirmed as naturally occurring in human atherosclerotic arteries and are categorized into a class of secosterols termed “Atheronals”, generated by ozonolysis of cholesterol's double bond to form a 5,6 secosterol as well as a secondary condensation product via aldolization.
Ozone has been implicated to have an adverse effect on plant growth, "...Ozone reduced total chlorophylls, carotenoid and carbohydrate concentration, and increased 1-aminocyclopropane-1-carboxylic acid (ACC) content and ethylene production. In treated plants, the ascorbate leaf pool was decreased, while lipid peroxidation and solute leakage were significantly higher than in ozone-free controls. The data indicated that ozone triggered protective mechanisms against oxidative stress in citrus."
Due to the strongly oxidizing properties of ozone, ozone is a primary irritant, affecting especially the eyes and respiratory systems and can be hazardous at even low concentrations. The Canadian Center for Occupation Safety and Health reports that:
"Even very low concentrations of ozone can be harmful to the upper respiratory tract and the lungs. The severity of injury depends on both by the concentration of ozone and the duration of exposure. Severe and permanent lung injury or death could result from even a very short-term exposure to relatively low concentrations." 
To protect workers potentially exposed to ozone, OSHA has established a permissible exposure limit (PEL) of 0.1 ppm (29 CFR 1910.1000 table Z-1), calculated as an 8 hour time weighted average. Higher concentrations are especially hazardous and NIOSH has established an Immediately Dangerous to Life and Health Limit (IDLH) of 5 ppm.  Work environments where ozone is used or where it is likely to be produced should have adequate ventilation and it is prudent to have a monitor for ozone that will alarm if the concentration exceeds the OSHA PEL. Continuous monitors for ozone are available from several suppliers.
Ozone often forms in nature under conditions where O2 will not react. Ozone used in industry is measured in g/Nm³ or weight percent. The regime of applied concentrations ranges from 1 to 5 weight percent in air and from 6 to 14 weight percent in oxygen.
This is the most popular type of ozone generator for most industrial and personal uses. While variations of the "hot spark" coronal discharge method of ozone production exist, including medical grade and industrial grade ozone generators, these units usually work by means of a corona discharge tube. They are typically very cost-effective and do not require an oxygen source other than the ambient air. However, they also produce nitrogen oxides as a by-product. Use of an air dryer can reduce or eliminate nitric acid formation by removing water vapor and increase ozone production. Use of an oxygen concentrator can further increase the ozone production and further reduce the risk of nitric acid formation by removing not only the water vapor, but also the bulk of the nitrogen..
UV ozone generators employ a light source that generates a narrow-band ultraviolet light, a subset of that produced by the Sun. The Sun's UV sustains the ozone layer in the stratosphere of Earth. While standard UV ozone generators tend to be less expensive, they usually produce ozone with a concentration of about 0.5% or lower. Another disadvantage of this method is that it requires the air (oxygen) to be exposed to the UV source for a longer amount of time, and any gas that is not exposed to the UV source will not be treated. This makes UV generators impractical for use in situations that deal with rapidly moving air or water streams (in-duct air sterilization, for example). Production of ozone is one of the potential dangers of ultraviolet germicidal irradiation.VUV Ozone generators are used in swimming pool and spa applications ranging to millions of gallons of water. VUV Ozone generators, unlike Corona Discharge generators) do not produce harmful nitrogen by-products and also unlike Corona Discharge systems, VUV Ozone generators work extremely well in humid air environments. There is also not normally a need for expensive off-gas mechanisms, and no need for air driers or oxygen concentrators which require extra costs and maintenance.
In the cold plasma method, pure oxygen gas is exposed to a plasmacreated by dielectric barrier discharge. The diatomic oxygen is split into single atoms, which then recombine in triplets to form ozone.
Cold plasma machines utilize pure oxygen as the input source and produce a maximum concentration of about 5% ozone. They produce far greater quantities of ozone in a given space of time compared to ultraviolet production. However, because cold plasma ozone generators are very expensive, they are found less frequently than the previous two types.
The discharges manifest as filamentary transfer of electrons (micro discharges) in a gap between two electrodes. In order to evenly distribute the micro discharges, a dielectric insulator must be used to separate the metallic electrodes and to prevent arcing.
Some cold plasma units also have the capability of producing short-lived allotropes of oxygen which include O4, O5, O6, O7, etc. These anions are even more reactive than ordinary O3.
Ozone cannot be stored and transported like other industrial gases (because it quickly decays into diatomic oxygen) and must therefore be produced on site. Available ozone generators vary in the arrangement and design of the high-voltage electrodes. At production capacities higher than 20 kg per hour, a gas/water tube heat-exchanger may be utilized as ground electrode and assembled with tubular high-voltage electrodes on the gas-side. The regime of typical gas pressures is around 2 bar absolute in oxygen and 3 bar absolute in air. Several megawatts of electrical power may be installed in large facilities, applied as one phase AC current at 50 to 8000 Hz and peak voltages between 3,000 and 20,000 volts. Applied voltage is usually inversely related to the applied frequency.
The dominating parameter influencing ozone generation efficiency is the gas temperature, which is controlled by cooling water temperature and/or gas velocity. The cooler the water, the better the ozone synthesis. The lower the gas velocity, the higher the concentration (but the lower the net ozone produced). At typical industrial conditions, almost 90% of the effective power is dissipated as heat and needs to be removed by a sufficient cooling water flow.
Because of the high reactivity of ozone, only few materials may be used like stainless steel (quality 316L), titanium, aluminium (as long as no moisture is present), glass, polytetrafluorethylene, or polyvinylidene fluoride. Viton may be used with the restriction of constant mechanical forces and absence of humidity (humidity limitations apply depending on the formulation). Hypalon may be used with the restriction that no water come in contact with it, except for normal atmospheric levels. Embrittlement or shrinkage is the common mode of failure of elastomers with exposure to ozone. Ozone cracking is the common mode of failure of elastomer seals like O-rings.
Ozone may be formed from O2 by electrical discharges and by action of high energy electromagnetic radiation. Certain electrical equipment generate significant levels of ozone. This is especially true of devices using high voltages, such as ionic air purifiers, laser printers, photocopiers, tasers and arc welders. Electric motors using brushes can generate ozone from repeated sparking inside the unit. Large motors that use brushes, such as those used by elevators or hydraulic pumps, will generate more ozone than smaller motors. Ozone is similarly formed in the Catatumbo lightning storms phenomenon on the Catatumbo River in Venezuela, which helps to replenish ozone in the upper troposhere. It is the world's largest single natural generator of ozone, lending calls for it to be designated a UNESCO World Heritage Site.
In the laboratory, ozone can be produced by electrolysis using a 9 volt battery, a pencil graphite rod cathode, a platinum wire anode and a 3 molar sulfuric acid electrolyte. The half cell reactions taking place are
It can also be prepared by passing 10,000-20,000 volts DC through dry O2. This can be done with an apparatus consisting of two concentric glass tubes sealed together at the top, with in and out spigots at the top and bottom of the outer tube. The inner core should have a length of metal foil inserted into it connected to one side of the power source. The other side of the power source should be connected to another piece of foil wrapped around the outer tube. Dry O2 should be run through the tube in one spigot. As the O2 is run through one spigot into the apparatus and 10,000-20,000 volts DC are applied to the foil leads, electricity will discharge between the dry dioxygen in the middle and form O3 and O2 out the other spigot. The reaction can be summarized as follows:
3 O2 — electricity → 2 O3
Some air filters and purifiers create ozone.
The largest use of ozone is in the preparation of pharmaceuticals, synthetic lubricants, as well as many other commercially useful organic compounds, where it is used to sever carbon-carbon bonds. It can also be used for bleaching substances and for killing microorganisms in air and water sources. Many municipal drinking water systems kill bacteria with ozone instead of the more common chlorine. Ozone has a very high oxidation potential. Ozone does not form organochlorine compounds, nor does it remain in the water after treatment. The Safe Drinking Water Act mandate that these systems introduce an amount of chlorine to maintain a minimum of 0.2 ppm residual Free Chlorine in the pipes, based on results of regular testing. Where electrical power is abundant, ozone is a cost-effective method of treating water, since it is produced on demand and does not require transportation and storage of hazardous chemicals. Once it has decayed, it leaves no taste or odor in drinking water.
Although low levels of ozone have been advertised to be of some disinfectant use in residential homes, the concentration of ozone in dry air required to have a rapid, substantial effect on airborne pathogens exceeds safe levels recommended by the U.S. Occupational Safety and Health Administration and Environmental Protection Agency. Humidity control can vastly improve both the killing power of the ozone and the rate at which it decays back to oxygen (more humidity allows more effectiveness). Spore forms of most pathogens are very tolerant of atmospheric ozone in concentrations where asthma patients start to have issues.
Industrially, ozone is used to: Disinfect laundry in hospitals, food factories, care homes etc; Disinfect water in place of chlorine Deodorize air and objects, such as after a fire. This process is extensively used in Fabric Restoration Kill bacteria on food or on contact surfaces; Sanitize swimming pools and spas Kill insects in stored grain Scrub yeast and mold spores from the air in food processing plants; Wash fresh fruits and vegetables to kill yeast, mold and bacteria; Chemically attack contaminants in water (iron, arsenic, hydrogen sulfide, nitrites, and complex organics lumped together as "colour"); Provide an aid to flocculation (agglomeration of molecules, which aids in filtration, where the iron and arsenic are removed); Manufacture chemical compounds via chemical synthesis Clean and bleach fabrics (the former use is utilized in Fabric Restoration; the latter use is patented); Assist in processing plastics to allow adhesion of inks; Age rubber samples to determine the useful life of a batch of rubber; Eradicate water borne parasites such as Giardia lamblia and Cryptosporidium in surface water treatment plants.
Many hospitals in the U.S. and around the world use large ozone generators to decontaminate operating rooms between surgeries. The rooms are cleaned and then sealed airtight before being filled with ozone which effectively kills or neutralizes all remaining bacteria.
Ozone is used as an alternative to chlorine or chlorine dioxide in the bleaching of wood pulp . It is often used in conjunction with oxygen and hydrogen peroxide to eliminate the need for chlorine-containing compounds in the manufacture of high-quality, white paper
Devices generating high levels of ozone, some of which use ionization, are used to sanitize and deodorize uninhabited buildings, rooms, ductwork, woodsheds, and boats and other vehicles.
In the U.S., air purifiers emitting lower levels of ozone have been sold. This kind of air purifier is sometimes claimed to imitate nature's way of purifying the air without filters and to sanitize both it and household surfaces. The United States Environmental Protection Agency (EPA) has declared that there is "evidence to show that at concentrations that do not exceed public health standards, ozone is not effective at removing many odor-causing chemicals" or "viruses, bacteria, mold, or other biological pollutants." Furthermore, its report states that "results of some controlled studies show that concentrations of ozone considerably higher than these [human safety] standards are possible even when a user follows the manufacturer’s operating instructions." The government successfully sued one company in 1995, ordering it to stop repeating health claims without supporting scientific studies.
Ozonated water is used to launder clothes and to sanitize food, drinking water, and surfaces in the home. According to the U.S. Food and Drug Administration (FDA), it is "amending the food additive regulations to provide for the safe use of ozone in gaseous and aqueous phases as an antimicrobial agent on food, including meat and poultry." Studies at California Polytechnic University demonstrated that 0.3 ppm levels of ozone dissolved in filtered tapwater can produce a reduction of more than 99.99% in such food-borne microorganisms as salmonella, E. coli 0157:H7, and Campylobacter. This quantity exceeds 20,000 times the WHO recommended limits stated above. Ozone can be used to remove pesticide residues from fruits and vegetables.
Ozone is used in homes and hot tubs to kill bacteria in the water and to reduce the amount of chlorine or bromine required by reactivating them to their free state. Since ozone does not remain in the water long enough, ozone by itself is ineffective at preventing cross-contamination among bathers and must be used in conjunction with these halogens. Gaseous ozone created by ultraviolet light or by corona discharge is injected into the water.
Ozone is also widely used in treatment of water in aquariums and fish ponds. Its use can minimize bacterial growth, control parasites, eliminate transmission of some diseases, and reduce or eliminate "yellowing" of the water. Ozone must not come in contact with fish's gill structures. Natural salt water (with life forms) provides enough "instantaneous demand" that controlled amounts of ozone activate bromide ion to hypobromous acid, and the ozone entirely decays in a few seconds to minutes. If oxygen fed ozone is used, the water will be higher in dissolved oxygen, fish's gill structures will atrophy and they will become dependent on higher dissolved oxygen levels.
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